By Richard C. Alkire, Charles W. Tobias

This sequence, previously edited by way of Heinz Gerischer and Charls V. Tobias, now edited by means of Richard C. Alkire and Dieter M. Kolb, has been warmly welcomed via scientists world-wide that's mirrored within the experiences of the former volumes: 'This is a vital booklet for researchers in electrochemistry; it covers components of either basic and sensible value, with reports of top quality. the cloth is especially good awarded and the alternative of subject matters displays a balanced editorial coverage that's welcomed.' The Analyst

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11. 10-diphenylanthracene (B). Potential energy curves are presented in the zero-order approximation, without removing the degeneracy at the crossing points of the potential energy curves. Broken lines represent the vibronically excited triplet state. converted in primary TTA may also take part in the triplet-triplet annihilation (real bimolecular, secondary TTA according to reaction (37)). Such a process leads, however, to much less efficient formation of the excited singlet states. The ECL efficiencies $eel reported for both hydrocarbons are fairly large (up to a few percent), at least an order of magnitude greater than those found for ECL processes occurring according to a “pure” T-route.

Kapturkiewicz I R++R- \ energy energy reaction coordinate - I reaction coordinate - Fig. 11. 10-diphenylanthracene (B). Potential energy curves are presented in the zero-order approximation, without removing the degeneracy at the crossing points of the potential energy curves. Broken lines represent the vibronically excited triplet state. converted in primary TTA may also take part in the triplet-triplet annihilation (real bimolecular, secondary TTA according to reaction (37)). Such a process leads, however, to much less efficient formation of the excited singlet states.

The shapes 22 A. Kapturkiewicz excited singlet excited triplet excited singlet excited triplet ground state ground state t t energy reaction coordinate - energy reaction coordinate - (C) excited ground t energy reaction coordinate - reaction coordinate - Fig. 8. Reaction coordinate diagram for different ECL processes (potential energy curves are presented in the zero-order approximation, without removing the degeneracy at the crossing points of the potential energy curves). (A) Single organic ECL system with direct formation of the excited singlet state (Sroute).

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